Preparasi Minyak Goreng Bekas sebagai Bahan Baku Pembuatan Biodiesel dengan Adsorben Arang Aktif dari Tempurung Kelapa

Authors

  • Haryono Departemen Kimia FMIPA Unpad

Keywords:

Indonesian

Abstract

Cooking oil, particularly from palm oil, is a primary need in households and the food and culinary industry. The use of this cooking oil ultimately results in waste in the form of waste cooking oil. Waste cooking oil has the potential to be used as a raw material in the production of biodiesel, a type of renewable energy. However, before being used in the biodiesel production process, the waste cooking oil must be separated from its impurities. One method in the impurity separation stage from waste cooking oil is adsorption with various types of adsorbents, such as activated charcoal. Coconut shells are a potential biomass waste as a raw material for producing activated charcoal. The aim of this study was to determine the effect of temperature and adsorbent content on the adsorption of waste cooking oil with activated charcoal from coconut shells on the characteristics of waste cooking oil as a raw material for biodiesel synthesis. The research procedure includes two main stages, namely the purification of waste cooking oil by sedimentation, filtration, evaporation, and sedimentation methods; then the synthesis of biodiesel from waste cooking oil after purification. The results of the study showed that the adsorption of waste cooking oil at a temperature of 70 °C and an activated charcoal content as an adsorbent of 5% (w/v) produced waste cooking oil with the best quality, based on the parameters of density, viscosity, acid number, and iodine number. Biodiesel produced from waste cooking oil that has been purified under optimal adsorption conditions has met the biodiesel quality standards according to Indonesian National Standard, SNI 7182-2015.

 

References

The Global Economy, Indonesia: Oil Production, Tersedia online di https://www.theglobaleconomy.com/Indonesia/oil_production/, Diakses pada 12 Oktober 2025.

L. Zhang, X. Jian, and Y. Ma, “Analysis of Differences in Fossil Fuel Consumption in the World Based on the Fractal Time Series and Complex Network”, Frontiers in Physics, vol. 12, no. 1457287, pp. 1-12, 2024. https://doi.org/10.3389/fphy.2024.1457287

PT Pertamina, Pertamina Energy Outlook 2023: Panduan Transisi Energi Indonesia, Jakarta: PT Pertamina, 2023.

Kementerian Energi dan Sumber Daya Mineral Republik Indonesia, Pemerintah Kejar Target Tingkatkan Bauran EBT, Tersedia online di https://www.esdm.go.id/id/media-center/arsip-berita/, Diakses pada 12 Oktober 2025.

A. Gaur, S. Mishra, S. Chowdhury, P. Baredar and P. Verma, “A Review on Factor Affecting Biodiesel Production from Waste Cooking Oil: An Indian Perspective”, Materials Today: Proceedings, vol. 46, pp. 5594-5600, 2020. https://doi.10.1016/j.matpr.2020.09.43 2

M. J. Costa, M. R. L. Silva, E. E. A. Ferreira, A. K. F. Carvalho, R. C. Basso, E. B. Pereira, H. F. de Castro, A. A. Mendes and D. B. Hirata, “Enzymatic Biodiesel Production by Hydroesterifichoation Using Waste Cooking Oil as Feedstock”, Chemical Engineering and Processing-Process Intensification, vol. 157, no. 108131, 2020. https://doi.org/10.1016/j.cep.2020.108131

S. F. Basumatary, B. Das, B. K. Das, M. Hoque, S. Brahma, B. Bidangshri, K. Patir, M. Selvaraj, S. L. Rokhum and S. Basumatary, “Recent Advances in Magnetic Solid Catalysts: Synthesis, Stabilization and Application in Cleaner Production of Biodiesel”, Energy Nexus, vol. 15, no. 100318, 2024. https://doi.org/10.1016/j.nexus.2024.100318

Monika, S. Banga and V. V. Pathak, “Biodiesel Production from Waste Cooking Oil: A Comprehensive Review on the Application of Heterogenous Catalysts”, Energy Nexus, vol. 10, no. 100209, pp. 1-20, 2023. https://doi.org/10.1016/j.nexus.2023.100209

Gabungan Pengusaha Kelapa Sawit Indonesia, Tersedia online di https://gapki.id/news/2025/03/06/produksi-menurun-pasar-indonesia-menyusut/, Diakses pada 12 Oktober 2025.

C. Adhikesavan, D. Ganesh, and V. Charles Augustin, “Effect of Quality of Waste Cooking Oil on the Properties of Biodiesel, Engine Performance and Emissions”, Cleaner Chemical Engineering, vol. 4, no. 100070, pp. 1-9, 2022. https://doi.org/10.1016/j.clce.2022.100070

M. U. H. Suzihaque, H. Alwi, U. K. Ibrahim, S. Abdullah, and N. Haron, “Biodiesel Production from Waste Cooking Oil: A Brief Review”, Materials Today: Proceedings, vol. 63, S490-S495, 2022. https://doi.org/10.1016/j.matpr.2022.04.527

H. Sanli, M. Canakci, and E. Alptekin, “Characterization of Waste Frying Oils Obtained from Fifferent Facilities”, World Renewable Energy Congress, Linkoping–Sweden 8-13 May 2011, p. 479-485.

V. Plata, D. Ferreira-Beltrán, and P. Gauthier-Maradei, “Effect of Cooking Conditions on Selected Properties of Biodiesel Produced from Palm-Based Waste Cooking Oils”, Energies, vol. 15, no. 3, p. 908, 2022. https://doi.org/10.3390/en15030908

N. I. Alias, K. Javendra, and M. Z. Shahrom, “Characterization of Waste Cooking Oil for Biodiesel Production”, Journal of Kejuruteraan, vol. 1, no. 2, pp. 79-83, 2018. http://dx.doi.org/10.17576/jkukm-2018-si1(2)-10

C. G. Lopresto, M. Gentile, A. Caravella, S. Candamano, and V. Calabro`, “De-acidification of Waste Cooking Oils by Adsorption on Industrial Waste: Kinetic Analysis of a Green Pretreatment for Biodiesel Production”, Chemosphere, vol. 380, 144460, 2025. https://doi.org/10.1016/j.chemosphere.2025.144460

R. Bostan, M. Glevitzky, S. Varvara, G. A. Dumitrel, G. I. Rusu, M. Popa, I. Glevitzky, and M. L. Vică, “Utilization of Natural Adsorbents in the Purification of Used Sunflower and Palm Cooking Oils”, Applied Sciences, vol. 14, no. 11, 4417, 2024. https://doi.org/10.3390/app14114417

L. Chandana, K. Krushnamurty, D. Suryakala, and Ch. Subrahmanyam, “Low-cost Adsorbent Derived from the Coconut Shell for the Removal of Hexavalent Chromium from Aqueous Medium”, Materials Today: Proceedings, vol. 26, no. 1, pp. 44-51, 2020. https://doi.org/10.1016/j.matpr.2019.04.205

S. A. Bello, J. O. Agunsoye, J. A. Adebisi, F. O. Kolawole, and S. B. Hassan, “Physical Properties of Coconut Shell Nanoparticles”, Katmandu University Journal of Science, Engineering, and Technology, vol. 12, no. 1, pp. 63-79, 2016.

M. Popa, I. Glevitzky, G.-A. Dumitrel, M. Glevitzky, and D. Popa, “Study on Peroxide Values for Different Oils and Factors Affecting the Quality of Sunflower Oil”, Land Reclam. Earth Obs. Surv. Environ. Eng., vol. 6, pp. 137-140, 2017.

M. Alaqarbeh, “Adsorption Phenomena: Definition, Mechanism, and Adsorption Types: Short Review”, RHAZES: Green and Applied Chemistry, vol. 13, pp. 43-51, 2021. http://dx.doi.org/10.48419/IMIST.PRSM/rhazes-v13.28283

Published

2025-11-25

How to Cite

Haryono (2025) “Preparasi Minyak Goreng Bekas sebagai Bahan Baku Pembuatan Biodiesel dengan Adsorben Arang Aktif dari Tempurung Kelapa”, ReTII, pp. 182–187. Available at: https://journal.itny.ac.id/index.php/ReTII/article/view/6280 (Accessed: 4June2026).