PENGARUH KARAKTERISTIK MINERALOGI TERHADAP KAPASITAS TUKAR KATION  ZEOLIT ALAM PACITAN, JAWA TIMUR

Wawan Budianta; I Wayan  Warmada; Makruf  Nurudin

doi:10.33579/krvtk.v8i1.4004

Wawan Budianta Universitas Gadjah Mada
I Wayan Warmada Departemen Teknik Geologi, Fakultas Teknik, Universitas Gadjah Mada
Makruf Nurudin Departemen Ilmu Tanah, Fakultas Pertanian, Universitas Gadjah Mada, Yogyakarta

DOI: https://doi.org/10.33579/krvtk.v8i1.4004

Abstract

The study aimed to investigate the influence of mineralogical and chemical composition on the cation exchange capacity of natural zeolite obtained from Pacitan, East Java. Ten natural zeolite samples were analyzed for mineralogical and chemical composition and cation exchange capacity. The result of the study showed that the natural zeolite samples have a mordenite-type mineral in dominant, with the percentage in vary between 32% to 38%. Based on chemical analysis, the natural zeolite samples consist of SiO₂ ranging from 61% to 66% and Al₂O₃ ranging from 9% to 11%, which are then calculated to obtain for Si/Al ratio. The value of cation exchange capacity obtained ranges from 70 meq/100 g to 91 meq/100 g, with 82 meq/100 g on average. This variation was most probably influenced by the difference in zeolite mineral type presence and other minerals. Moedenite mineral type was suspected as the most dominant, which influenced the cation exchange capacity value obtained in this study. The cation exchange capacity of the samples gives a positive correlation to the content of the mordenite mineral, total microporous mineral, and Si/Al ratio. The result of the study is expected to contribute to the information on the natural zeolite in the area for agricultural and environmental fields.

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References

E. Cataldo, L. Salvi, F. Paoli, M. Fucile, G. Masciandaro, and D. Manzi., “Application of zeolites in agriculture and other potential uses: a review,” Agronomy, vol. 11, no. 8, pp. 1547, 2021. https://doi.org/10.3390/agronomy11081547.

Y. Lv, B. Ma, Y. Liu, C. Wang, and Y. Chen, “Adsorption behavior and mechanism of mixed heavy metal ions by zeolite adsorbent prepared from lithium leach residue,” Microporous Mesoporous Mater., vol. 329, pp. 111553, 2022 https://doi.org/10.1016/j.micromeso.2021.111553.

E. Pérez-Botella, S. Valencia, and F. Rey, “Zeolites in adsorption processes: state of the art and future prospects,” Chem. Rev., vol. 122, no. 24, pp. 17647–17695, 2022. https://doi.org/10.1021/acs.chemrev.2c00140.

K. Kusdarto, "Potensi zeolit di Indonesia," Jurnal Zeolit Indonesia, vol. 7, no. 2, 78-87, 2008.

K. M. Manjaiah, R. Mukhopadhyay, R. Paul, S. C. Datta, P. Kumararaja, and B. Sarkar, Clay minerals and zeolites for environmentally sustainable agriculture, in Modified Clay and Zeolite Nanocomposite Materials, M. Mercurio, B. Sarkar, and A. Langella, Ed. Elsevier, pp. 309–329, 2019. https://doi.org/10.1016/B978-0-12-814617-0.00008-6.

L. Kruszewski, V. Palchik, Y. Vapnik, K. Nowak, K. Banasik, I. Galuskina, I. "Mineralogical, geochemical, and rock mechanic characteristics of zeolite-bearing rocks of the hatrurim basin, Israel," Minerals, vol. 11, no. 10, 1062, 2021. https://doi.org/10.3390/min11101062.

Asrafil, A. Idrus, and D. Wintolo, “Eksplorasi endapan hidrotermal di Daerah Kasihan, Pacitan, Jawa Timur,” J. Geol. dan Sumberd. Miner., vol. 18, no. 4, pp. 191–200, 2017.

G. P. Gillman and E. A. Sumpter, “Modification to the Compulsive Exchange Method for Measuring Exchange Characteristics of Soils,” Soil Res., vol. 24, no. 1, pp. 61–66, 1986.

A. Alshameri, W. Xinghu, A. S. Dawood, C. Xin, C. Yan, and A. M. Assabri, “Characterization of Yemeni Natural Zeolite (Al-Ahyuq Area) and its environment applications: a review,” J. Ecol. Eng., vol. 20, no. 4, pp. 157–166, 2019. https://doi.org/10.12911/22998993/102842.

P. C. Piilonen, G. Poirier, W. Lechner, R. Rowe, and R. P. Richards, “Zeolite minerals from Wat Ocheng, Ta Ang, Ratanakiri Province, Cambodia - occurrence, composition, and paragenesis,” Can. Mineral., vol. 60, no. 1, pp. 133–153, 2022. https://doi.org/10.3749/canmin.2000113.

J. L. Costafreda and D. A. Martín, “New deposit of Mordenite–Clinoptilolite in the Eastern Region of Cuba: uses as pozzolans,” Molecules, vol. 26, no. 15, pp. 4676, 2022. https://doi.org/10.3390/molecules26154676.

A. Vural and M. Albayrak, “Evaluation of gördes zeolites in terms of mineralogical, geochemical and environmental effects,” J. Eng. Res. Appl. Sci., vol. 9, no. 2, pp. 1503–1520, 2020. http://journaleras.com/index.php/jeras/article/view/216.

C. Covarrubias, R. García, R. Arriagada, J. Yánez, and M. T. Garland, “Cr(III) Exchange on zeolites obtained from kaolin and natural mordenite,” Microporous Mesoporous Mater., vol. 88, no. 1–3, pp. 220–231, 2006.

A. F. Gualtieri, E. Marchi, and E. Passaglia, “Zeolite content and cation exchange capacity of zeolite-rich rocks,” in Studies in Surface Science and Catalysis, vol. 125, Elsevier Science B.V., pp. 707–713, 1999.

F. Morante-Carballo, N. Montalván-Burbano, P. Carrión-Mero, and N. Espinoza-Santos, “Cation exchange of natural zeolites: worldwide research,” Sustainability, vol. 13, no. 14, pp. 7751, 2021 https://doi.org/10.3390/su13147751.

A. Filippidis, N. Kantiranis, M. Stamatakis, A. Drakoulis, and E. Tzamos, “The cation exchange capacity of the greek zeolitic rocks,” Bull. Geol. Soc. Greece, vol. 40, no. 2, pp. 723–735, 2007.

D. A. Holmes, “Zeolites,” in Industrial Minerals and Rocks, 6th Editio., D. D. Carr, Ed. Littleton: Society for Mining, Metallurgy, and Exploration, pp. 1129–1158, 1994.

I. Friberg, N. Sadokhina, and L. Olsson, “The effect of Si/Al ratio of zeolite supported pd for complete CH4 oxidation in the presence of water vapor and SO2,” Appl. Catal. B Environ., vol. 250, pp. 117–131, 2019. https://doi.org/10.1016/j.apcatb.2019.03.005.

Ç. Ceylan, “Geological, mineralogical, geochemical properties, and characterization of marine zeolite,” J. Ongoing Chem. Res., vol. 6, no. 1, pp. 10–14, 2021.